IndiumV3, Chine, Analysis, bibRecord, 001669

Designed formation of the stable adduct InP/CTAB/Clay

Identifieur interne : 001669 ( Chine/Analysis ); précédent : 001668; suivant : 001670

Designed formation of the stable adduct InP/CTAB/Clay

Auteurs : RBID : Pascal:06-0201661

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Spectre absorption, Echange ion, Autoassemblage, Exfoliation, Diffraction RX, Microscopie électronique transmission, Spectre UV visible, Multicouche, Composé addition, Indium phosphure, Argile, Polyélectrolyte, Nanocristal, Nanomatériau, InP, In P, 8235R, 8107B, 8239W.

English descriptors

KwdEn :
- Absorption spectrum, Adduct, Clay, Exfoliation, Experimental study, Indium phosphide, Ion exchange, Multiple layer, Nanocrystal, Nanostructured materials, Polyelectrolyte, Self assembly, Transmission electron microscopy, Ultraviolet visible spectrum, X ray diffraction.

Abstract

An ordered multilayered adduct InP/CTAB/Clay has been synthesized via simple ion-exchange route that utilizes the electrostatic self-assembly between the exfoliated sodium montmorillonite nanoplatelets and the substituted InP/CTAB cationic polyelectrolytes. The obtained samples exhibit a high degree of structural ordering, with the interlammellar spacing of ca. 36.8 A, which is well manifested by low-angle X-ray powder diffraction (LXRD) patterns. Transmission electron microscopy (TEM) images indicate its structural hierarchy, while UV-Vis and PL spectrum demonstrates the existence of InP nanocrystals. It is found that the high CEC of Na-montmorillonite and the appropriate ratio of CTAB-to-InP, as well as the presence of the InP/CTAB polyelectrolytes would have the influence on the purity and the formation of the stable adducts InP/CTAB/Clay. This preparative method described here can be anticipated to offer a potential strategy for building the ordered stable adducts with sandwich-like structures due to its ease, reproducibility and versatility.

Links toward previous steps (curation, corpus...)

to stream Main, to step Corpus: 009175
to stream Main, to step Repository: 008E73
to stream Chine, to step Extraction: 001669

Links to Exploration step

Pascal:06-0201661

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Designed formation of the stable adduct InP/CTAB/Clay</title>
<author><name>XUCHU MA</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Science and Technology of China</s1>
<s2>Hefei, Anhui 230026</s2>
<s3>CHN</s3>
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<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Hefei, Anhui 230026</wicri:noRegion>
</affiliation>
</author>
<author><name>FEN XU</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory of Inorganic Materials Chemistry, The University of Namur (FUNDP), 61 rue de Bruxelles</s1>
<s2>5000 Namur</s2>
<s3>BEL</s3>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Belgique</country>
<wicri:noRegion>5000 Namur</wicri:noRegion>
</affiliation>
</author>
<author><name>LIYONG CHEN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Science and Technology of China</s1>
<s2>Hefei, Anhui 230026</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Hefei, Anhui 230026</wicri:noRegion>
</affiliation>
</author>
<author><name>ZHONGYONG YUAN</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>College of Chemistry, Nankai University</s1>
<s2>Tianjin 300071</s2>
<s3>CHN</s3>
<sZ>4 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Tianjin 300071</wicri:noRegion>
</affiliation>
</author>
<author><name>ZUDE ZHANG</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Science and Technology of China</s1>
<s2>Hefei, Anhui 230026</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Hefei, Anhui 230026</wicri:noRegion>
</affiliation>
</author>
<author><name>JUE QIAN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Science and Technology of China</s1>
<s2>Hefei, Anhui 230026</s2>
<s3>CHN</s3>
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<country>République populaire de Chine</country>
<wicri:noRegion>Hefei, Anhui 230026</wicri:noRegion>
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</author>
<author><name>YI XIE</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Science and Technology of China</s1>
<s2>Hefei, Anhui 230026</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Hefei, Anhui 230026</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">06-0201661</idno>
<date when="2006">2006</date>
<idno type="stanalyst">PASCAL 06-0201661 INIST</idno>
<idno type="RBID">Pascal:06-0201661</idno>
<idno type="wicri:Area/Main/Corpus">009175</idno>
<idno type="wicri:Area/Main/Repository">008E73</idno>
<idno type="wicri:Area/Chine/Extraction">001669</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0022-0248</idno>
<title level="j" type="abbreviated">J. cryst. growth</title>
<title level="j" type="main">Journal of crystal growth</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption spectrum</term>
<term>Adduct</term>
<term>Clay</term>
<term>Exfoliation</term>
<term>Experimental study</term>
<term>Indium phosphide</term>
<term>Ion exchange</term>
<term>Multiple layer</term>
<term>Nanocrystal</term>
<term>Nanostructured materials</term>
<term>Polyelectrolyte</term>
<term>Self assembly</term>
<term>Transmission electron microscopy</term>
<term>Ultraviolet visible spectrum</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Spectre absorption</term>
<term>Echange ion</term>
<term>Autoassemblage</term>
<term>Exfoliation</term>
<term>Diffraction RX</term>
<term>Microscopie électronique transmission</term>
<term>Spectre UV visible</term>
<term>Multicouche</term>
<term>Composé addition</term>
<term>Indium phosphure</term>
<term>Argile</term>
<term>Polyélectrolyte</term>
<term>Nanocristal</term>
<term>Nanomatériau</term>
<term>InP</term>
<term>In P</term>
<term>8235R</term>
<term>8107B</term>
<term>8239W</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">An ordered multilayered adduct InP/CTAB/Clay has been synthesized via simple ion-exchange route that utilizes the electrostatic self-assembly between the exfoliated sodium montmorillonite nanoplatelets and the substituted InP/CTAB cationic polyelectrolytes. The obtained samples exhibit a high degree of structural ordering, with the interlammellar spacing of ca. 36.8 A, which is well manifested by low-angle X-ray powder diffraction (LXRD) patterns. Transmission electron microscopy (TEM) images indicate its structural hierarchy, while UV-Vis and PL spectrum demonstrates the existence of InP nanocrystals. It is found that the high CEC of Na-montmorillonite and the appropriate ratio of CTAB-to-InP, as well as the presence of the InP/CTAB polyelectrolytes would have the influence on the purity and the formation of the stable adducts InP/CTAB/Clay. This preparative method described here can be anticipated to offer a potential strategy for building the ordered stable adducts with sandwich-like structures due to its ease, reproducibility and versatility.</div>
</front>
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<fA03 i2="1"><s0>J. cryst. growth</s0>
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<fA06><s2>1</s2>
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<fA08 i1="01" i2="1" l="ENG"><s1>Designed formation of the stable adduct InP/CTAB/Clay</s1>
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<fA11 i1="01" i2="1"><s1>XUCHU MA</s1>
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<fA11 i1="02" i2="1"><s1>FEN XU</s1>
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<fA11 i1="03" i2="1"><s1>LIYONG CHEN</s1>
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<fA11 i1="04" i2="1"><s1>ZHONGYONG YUAN</s1>
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<fA11 i1="05" i2="1"><s1>ZUDE ZHANG</s1>
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<fA11 i1="06" i2="1"><s1>JUE QIAN</s1>
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<fA14 i1="01"><s1>Department of Chemistry, University of Science and Technology of China</s1>
<s2>Hefei, Anhui 230026</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
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<fA14 i1="02"><s1>Laboratory of Inorganic Materials Chemistry, The University of Namur (FUNDP), 61 rue de Bruxelles</s1>
<s2>5000 Namur</s2>
<s3>BEL</s3>
<sZ>2 aut.</sZ>
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<fA14 i1="03"><s1>College of Chemistry, Nankai University</s1>
<s2>Tianjin 300071</s2>
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<sZ>4 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>An ordered multilayered adduct InP/CTAB/Clay has been synthesized via simple ion-exchange route that utilizes the electrostatic self-assembly between the exfoliated sodium montmorillonite nanoplatelets and the substituted InP/CTAB cationic polyelectrolytes. The obtained samples exhibit a high degree of structural ordering, with the interlammellar spacing of ca. 36.8 A, which is well manifested by low-angle X-ray powder diffraction (LXRD) patterns. Transmission electron microscopy (TEM) images indicate its structural hierarchy, while UV-Vis and PL spectrum demonstrates the existence of InP nanocrystals. It is found that the high CEC of Na-montmorillonite and the appropriate ratio of CTAB-to-InP, as well as the presence of the InP/CTAB polyelectrolytes would have the influence on the purity and the formation of the stable adducts InP/CTAB/Clay. This preparative method described here can be anticipated to offer a potential strategy for building the ordered stable adducts with sandwich-like structures due to its ease, reproducibility and versatility.</s0>
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<fC02 i1="01" i2="X"><s0>001D09D04F</s0>
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<s5>02</s5>
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<s5>02</s5>
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<s5>02</s5>
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<s5>03</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Autoassemblage</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Self assembly</s0>
<s5>05</s5>
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<fC03 i1="04" i2="X" l="SPA"><s0>Autoensamble</s0>
<s5>05</s5>
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<fC03 i1="05" i2="X" l="FRE"><s0>Exfoliation</s0>
<s5>06</s5>
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<fC03 i1="05" i2="X" l="ENG"><s0>Exfoliation</s0>
<s5>06</s5>
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<s5>06</s5>
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<s5>07</s5>
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<s5>07</s5>
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<s5>07</s5>
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<s5>08</s5>
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<fC03 i1="07" i2="X" l="ENG"><s0>Transmission electron microscopy</s0>
<s5>08</s5>
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<s5>08</s5>
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<s5>09</s5>
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<fC03 i1="08" i2="X" l="ENG"><s0>Ultraviolet visible spectrum</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Espectro UV visible</s0>
<s5>09</s5>
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<fC03 i1="09" i2="X" l="FRE"><s0>Multicouche</s0>
<s5>15</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Multiple layer</s0>
<s5>15</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Capa múltiple</s0>
<s5>15</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Composé addition</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Adduct</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Compuesto adición</s0>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Indium phosphure</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Indium phosphide</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Indio fosfuro</s0>
<s5>17</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Argile</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Clay</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Arcilla</s0>
<s5>18</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Polyélectrolyte</s0>
<s5>19</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Polyelectrolyte</s0>
<s5>19</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Polielectrolito</s0>
<s5>19</s5>
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<fC03 i1="14" i2="X" l="FRE"><s0>Nanocristal</s0>
<s5>20</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Nanocrystal</s0>
<s5>20</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Nanocristal</s0>
<s5>20</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Nanomatériau</s0>
<s5>21</s5>
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<fC03 i1="15" i2="3" l="ENG"><s0>Nanostructured materials</s0>
<s5>21</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>InP</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>In P</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>8235R</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
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<fC03 i1="19" i2="X" l="FRE"><s0>8107B</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE"><s0>8239W</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>58</s5>
</fC03>
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<s5>48</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Inorganic compound</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Compuesto inorgánico</s0>
<s5>48</s5>
</fC07>
<fC07 i1="02" i2="X" l="FRE"><s0>Composé organique</s0>
<s2>NA</s2>
<s5>49</s5>
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<fC07 i1="02" i2="X" l="ENG"><s0>Organic compounds</s0>
<s2>NA</s2>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="X" l="SPA"><s0>Compuesto orgánico</s0>
<s2>NA</s2>
<s5>49</s5>
</fC07>
<fN21><s1>128</s1>
</fN21>
<fN44 i1="01"><s1>PSI</s1>
</fN44>
<fN82><s1>PSI</s1>
</fN82>
</pA>
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   |texte=   Designed formation of the stable adduct InP/CTAB/Clay
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Designed formation of the stable adduct InP/CTAB/Clay

Designed formation of the stable adduct InP/CTAB/Clay

Descripteurs français

English descriptors

Abstract

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